MLchartDataset catalogue

Alkylidenes

Term · Chemistry · MLC-T-CHM-000408

Carbenes of the form R2C: formed by replacing one or both hydrogens of methylene with alkyl groups, such as propylidene, CH3CH2CH:. The carbon is divalent with only six valence electrons, so these are short-lived reactive intermediates. They differ from alkylidene groups, the divalent substituents written =CR2, which attach to another atom through a double bond.

Table 1. Record
IdentifierMLC-T-CHM-000408
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1314 (https://doi.org/10.1351/pac199567081307)
See alsoCarbenes
Record as JSON
{
  "id": "MLC-T-CHM-000408",
  "term": "Alkylidenes",
  "field": "Chemistry",
  "definition": "Carbenes of the form R2C: formed by replacing one or both hydrogens of methylene with alkyl groups, such as propylidene, CH3CH2CH:. The carbon is divalent with only six valence electrons, so these are short-lived reactive intermediates. They differ from alkylidene groups, the divalent substituents written =CR2, which attach to another atom through a double bond.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "carbenes"
  ],
  "references": [
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1314 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/alkylidenes/"
}

Record 432 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.