Carbenes
Term · Chemistry · MLC-T-CHM-001622
Neutral compounds containing a divalent carbon atom that has six valence electrons, two of which are non-bonding. These highly reactive species act as intermediates in chemical reactions, including insertions into C-H bonds and additions to double bonds to form cyclopropanes. The simplest carbene is methylene (:CH2), which exists in either a singlet or a triplet electronic state with different geometries and reactivities.
| Identifier | MLC-T-CHM-001622 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| References | PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1324 (https://doi.org/10.1351/pac199567081307) |
| See also | Acyl carbenes; Hydrocarbons; Imidoyl carbenes; Parent hydride; Singlet state; Systematic name; Triplet state; Vinyl carbenes |
Record as JSON
{
"id": "MLC-T-CHM-001622",
"term": "Carbenes",
"field": "Chemistry",
"definition": "Neutral compounds containing a divalent carbon atom that has six valence electrons, two of which are non-bonding. These highly reactive species act as intermediates in chemical reactions, including insertions into C-H bonds and additions to double bonds to form cyclopropanes. The simplest carbene is methylene (:CH2), which exists in either a singlet or a triplet electronic state with different geometries and reactivities.",
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"acyl carbenes",
"hydrocarbons",
"imidoyl carbenes",
"parent hydride",
"singlet state",
"systematic name",
"triplet state",
"vinyl carbenes"
],
"references": [
"PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1324 (https://doi.org/10.1351/pac199567081307)"
],
"url": "https://mlchart.com/terminology/chemistry/carbenes/"
}
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