MLchartDataset catalogue

Anisotropic Raman scattering

Term · Chemistry · MLC-T-CHM-000619

Raman scattering that comes from the anisotropic component of the derived polarizability tensor, as distinct from its isotropic component. In samples of randomly oriented molecules it supplies the depolarized part of a band, and purely anisotropic scattering from nontotally symmetric vibrations has a depolarization ratio of 0.75. It carries information on molecular symmetry and on orientation in ordered samples.

Table 1. Record
IdentifierMLC-T-CHM-000619
FieldChemistry
SubjectAnalytical Chemistry
ReferencesPAC, 2021, 93, 647. 'Glossary of methods and terms used in analytical spectroscopy (IUPAC Recommendations 2019)' on page 738 (https://doi.org/10.1515/pac-2019-0203)
See alsoRaman scattering
Record as JSON
{
  "id": "MLC-T-CHM-000619",
  "term": "Anisotropic Raman scattering",
  "field": "Chemistry",
  "definition": "Raman scattering that comes from the anisotropic component of the derived polarizability tensor, as distinct from its isotropic component. In samples of randomly oriented molecules it supplies the depolarized part of a band, and purely anisotropic scattering from nontotally symmetric vibrations has a depolarization ratio of 0.75. It carries information on molecular symmetry and on orientation in ordered samples.",
  "subject": "Analytical Chemistry",
  "see_also": [
    "Raman scattering"
  ],
  "references": [
    "PAC, 2021, 93, 647. 'Glossary of methods and terms used in analytical spectroscopy (IUPAC Recommendations 2019)' on page 738 (https://doi.org/10.1515/pac-2019-0203)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/anisotropic-raman-scattering/"
}

Record 662 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.