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Arsanylium ions

Term · Chemistry · MLC-T-CHM-012887

The arsanyl cation H2As+ and its substitution derivatives R2As+, in which a two-coordinate arsenic atom carries a positive charge, a lone pair, and two substituents. They arise formally by removing a hydride or another anionic group from an arsane or an R2As-X compound, and they are arsenic analogues of phosphenium and nitrenium ions. They should not be confused with arsinylium ions, H2As(=O)+, which are acylium-type cations derived from arsinic acid.

Table 1. Record
IdentifierMLC-T-CHM-012887
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1319 (https://doi.org/10.1351/pac199567081307)
See alsoCation
Record as JSON
{
  "id": "MLC-T-CHM-012887",
  "term": "Arsanylium ions",
  "field": "Chemistry",
  "definition": "The arsanyl cation H2As+ and its substitution derivatives R2As+, in which a two-coordinate arsenic atom carries a positive charge, a lone pair, and two substituents. They arise formally by removing a hydride or another anionic group from an arsane or an R2As-X compound, and they are arsenic analogues of phosphenium and nitrenium ions. They should not be confused with arsinylium ions, H2As(=O)+, which are acylium-type cations derived from arsinic acid.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "cation"
  ],
  "references": [
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1319 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/arsanylium-ions/"
}

Record 849 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.