Iminylium ions
Term · Chemistry · MLC-T-CHM-005613
Cations of the type R2C=N+, in which a nitrogen carrying only one substituent, the doubly bonded carbon, bears the positive charge, making them a subclass of nitrenium ions. They are also called alkylideneaminylium ions, are strongly electrophilic and short-lived, and differ from iminium ions, whose nitrogen carries two further substituents and is not electron deficient.
| Identifier | MLC-T-CHM-005613 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| References | PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1344 (https://doi.org/10.1351/pac199567081307) |
| See also | Nitrenium ions |
Record as JSON
{
"id": "MLC-T-CHM-005613",
"term": "Iminylium ions",
"field": "Chemistry",
"definition": "Cations of the type R2C=N+, in which a nitrogen carrying only one substituent, the doubly bonded carbon, bears the positive charge, making them a subclass of nitrenium ions. They are also called alkylideneaminylium ions, are strongly electrophilic and short-lived, and differ from iminium ions, whose nitrogen carries two further substituents and is not electron deficient.",
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"nitrenium ions"
],
"references": [
"PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1344 (https://doi.org/10.1351/pac199567081307)"
],
"url": "https://mlchart.com/terminology/chemistry/iminylium-ions/"
}
Record 5,955 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.