Isodiazenes
Term · Chemistry · MLC-T-CHM-006177
Compounds of the type R2N+=N-, in which both substituents sit on one nitrogen and the other nitrogen carries none, making them isomers of diazenes, RN=NR. They are also called diazanylidenes or hydrazinylidenes, while names such as 1,1-diazene and aminonitrene are discouraged. They are reactive intermediates, typically generated by oxidizing 1,1-disubstituted hydrazines, that either lose nitrogen gas or dimerize to tetrazenes.
| Identifier | MLC-T-CHM-006177 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| Synonyms | azamines; diazanylidenes; hydrazinylidenes |
| References | PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1344 (https://doi.org/10.1351/pac199567081307) |
| See also | Carbenes; Trivial name |
Record as JSON
{
"id": "MLC-T-CHM-006177",
"term": "Isodiazenes",
"field": "Chemistry",
"definition": "Compounds of the type R2N+=N-, in which both substituents sit on one nitrogen and the other nitrogen carries none, making them isomers of diazenes, RN=NR. They are also called diazanylidenes or hydrazinylidenes, while names such as 1,1-diazene and aminonitrene are discouraged. They are reactive intermediates, typically generated by oxidizing 1,1-disubstituted hydrazines, that either lose nitrogen gas or dimerize to tetrazenes.",
"synonyms": [
"azamines",
"diazanylidenes",
"hydrazinylidenes"
],
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"carbenes",
"trivial name"
],
"references": [
"PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1344 (https://doi.org/10.1351/pac199567081307)"
],
"url": "https://mlchart.com/terminology/chemistry/isodiazenes/"
}
Record 6,558 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.