Iminyl radicals
Term · Chemistry · MLC-T-CHM-005612
Neutral organic radicals containing an unpaired electron on a nitrogen atom that is double-bonded to a carbon atom. These species are highly reactive and are typically generated by the homolytic cleavage of N-X bonds or by the addition of radicals to nitriles. Iminyl radicals participate in numerous reactions, including cyclizations and additions to unsaturated systems.
| Identifier | MLC-T-CHM-005612 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| References | PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1343 (https://doi.org/10.1351/pac199567081307) |
| See also | Radical; Alkylideneaminyl radicals; Aminyl radicals |
Record as JSON
{
"id": "MLC-T-CHM-005612",
"term": "Iminyl radicals",
"field": "Chemistry",
"definition": "Neutral organic radicals containing an unpaired electron on a nitrogen atom that is double-bonded to a carbon atom. These species are highly reactive and are typically generated by the homolytic cleavage of N-X bonds or by the addition of radicals to nitriles. Iminyl radicals participate in numerous reactions, including cyclizations and additions to unsaturated systems.",
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"radical",
"alkylideneaminyl radicals",
"aminyl radicals"
],
"references": [
"PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1343 (https://doi.org/10.1351/pac199567081307)"
],
"url": "https://mlchart.com/terminology/chemistry/iminyl-radicals/"
}
Record 5,954 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.