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Alkylideneaminoxyl radicals

Term · Chemistry · MLC-T-CHM-000406

Radicals of the form R2C=N-O with the unpaired electron on the oxygen end of a single N-O bond and a double bond from nitrogen to carbon. They are also called iminoxyl radicals and form when an oxime loses its hydroxyl hydrogen atom, for example on oxidation. Their EPR spectra show a large nitrogen hyperfine splitting.

Table 1. Record
IdentifierMLC-T-CHM-000406
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1314 (https://doi.org/10.1351/pac199567081307)
See alsoRadical; Iminoxyl radicals
Record as JSON
{
  "id": "MLC-T-CHM-000406",
  "term": "Alkylideneaminoxyl radicals",
  "field": "Chemistry",
  "definition": "Radicals of the form R2C=N-O with the unpaired electron on the oxygen end of a single N-O bond and a double bond from nitrogen to carbon. They are also called iminoxyl radicals and form when an oxime loses its hydroxyl hydrogen atom, for example on oxidation. Their EPR spectra show a large nitrogen hyperfine splitting.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "radical",
    "iminoxyl radicals"
  ],
  "references": [
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1314 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/alkylideneaminoxyl-radicals/"
}

Record 430 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.