Arsanylidenes
Term · Chemistry · MLC-T-CHM-000793
Carbene analogues of the form R-As:, in which a monosubstituted arsenic atom carries a lone pair and two further nonbonding electrons, leaving six electrons around arsenic. The parent H-As: is arsanylidene, with arsinidene as a common non-IUPAC synonym and arsinediyl as the former recommended name. They are reactive intermediates, the arsenic counterparts of carbenes and nitrenes.
| Identifier | MLC-T-CHM-000793 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| Synonyms | arsinidenes |
| References | PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1319 (https://doi.org/10.1351/pac199567081307) |
| See also | Carbene analogues |
Record as JSON
{
"id": "MLC-T-CHM-000793",
"term": "Arsanylidenes",
"field": "Chemistry",
"definition": "Carbene analogues of the form R-As:, in which a monosubstituted arsenic atom carries a lone pair and two further nonbonding electrons, leaving six electrons around arsenic. The parent H-As: is arsanylidene, with arsinidene as a common non-IUPAC synonym and arsinediyl as the former recommended name. They are reactive intermediates, the arsenic counterparts of carbenes and nitrenes.",
"synonyms": [
"arsinidenes"
],
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"carbene analogues"
],
"references": [
"PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1319 (https://doi.org/10.1351/pac199567081307)"
],
"url": "https://mlchart.com/terminology/chemistry/arsanylidenes/"
}
Record 848 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.