Stibanylidenes
Term · Chemistry · MLC-T-CHM-011409
Reactive antimony species of the formula RSb:, in which antimony carries one organic substituent, named as carbene analogues and best viewed as the heavy-pnictogen counterpart of a nitrene or phosphinidene. They are typically seen only as transient species, or as ligands stabilized by bulky groups or by a transition metal. The older IUPAC name was stibinediyl, and stibinidene is a common non-IUPAC synonym.
| Identifier | MLC-T-CHM-011409 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| Synonyms | stibinidenes |
| References | PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1367 (https://doi.org/10.1351/pac199567081307) |
| See also | Carbene analogues |
Record as JSON
{
"id": "MLC-T-CHM-011409",
"term": "Stibanylidenes",
"field": "Chemistry",
"definition": "Reactive antimony species of the formula RSb:, in which antimony carries one organic substituent, named as carbene analogues and best viewed as the heavy-pnictogen counterpart of a nitrene or phosphinidene. They are typically seen only as transient species, or as ligands stabilized by bulky groups or by a transition metal. The older IUPAC name was stibinediyl, and stibinidene is a common non-IUPAC synonym.",
"synonyms": [
"stibinidenes"
],
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"carbene analogues"
],
"references": [
"PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1367 (https://doi.org/10.1351/pac199567081307)"
],
"url": "https://mlchart.com/terminology/chemistry/stibanylidenes/"
}
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