Bunnett-Olsen equations

{
  "id": "MLC-T-CHM-001541",
  "term": "Bunnett-Olsen equations",
  "field": "Chemistry",
  "definition": "A set of linear free energy relationships used to analyze the protonation behavior of weak bases in strongly acidic solutions. These equations correlate the observed acidity constant with the acidity function and a parameter reflecting the solvation changes during protonation. They provide insight into the mechanism of proton transfer reactions.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "Cox-Yates equation",
    "acidity function"
  ],
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1091 (https://doi.org/10.1351/pac199466051077)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/bunnett-olsen-equations/"
}