MLchartDataset catalogue

Diradicals

Term · Chemistry · MLC-T-CHM-003246

Molecular species possessing two unpaired electrons, where the two radical centers are sufficiently separated that they do not strongly interact. These can exist in either a singlet state, where the electron spins are paired, or a triplet state, where the spins are parallel. The energy difference between these states dictates their reactivity and spectroscopic properties.

Table 1. Record
IdentifierMLC-T-CHM-003246
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1333 (https://doi.org/10.1351/pac199567081307)
See alsoBiradical; Singlet state; Triplet state
Record as JSON
{
  "id": "MLC-T-CHM-003246",
  "term": "Diradicals",
  "field": "Chemistry",
  "definition": "Molecular species possessing two unpaired electrons, where the two radical centers are sufficiently separated that they do not strongly interact. These can exist in either a singlet state, where the electron spins are paired, or a triplet state, where the spins are parallel. The energy difference between these states dictates their reactivity and spectroscopic properties.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "biradical",
    "singlet state",
    "triplet state"
  ],
  "references": [
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1333 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/diradicals/"
}

Record 3,452 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.