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Epimerization

Term · Chemistry · MLC-T-CHM-004028

A stereochemical transformation in which one epimer is converted into another. This process involves the inversion of configuration at only one chiral center in a molecule that has multiple chiral centers. Epimerization often occurs under acidic or basic conditions and can lead to a mixture of epimers at equilibrium.

Table 1. Record
IdentifierMLC-T-CHM-004028
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1114 (https://doi.org/10.1351/pac199466051077); PAC, 1996, 68, 2193. 'Basic terminology of stereochemistry (IUPAC Recommendations 1996)' on page 2208 (https://doi.org/10.1351/pac199668122193)
See alsoEpimers
Record as JSON
{
  "id": "MLC-T-CHM-004028",
  "term": "Epimerization",
  "field": "Chemistry",
  "definition": "A stereochemical transformation in which one epimer is converted into another. This process involves the inversion of configuration at only one chiral center in a molecule that has multiple chiral centers. Epimerization often occurs under acidic or basic conditions and can lead to a mixture of epimers at equilibrium.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "epimers"
  ],
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1114 (https://doi.org/10.1351/pac199466051077)",
    "PAC, 1996, 68, 2193. 'Basic terminology of stereochemistry (IUPAC Recommendations 1996)' on page 2208 (https://doi.org/10.1351/pac199668122193)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/epimerization/"
}

Record 4,265 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.