Walden inversion
Term · Chemistry · MLC-T-CHM-012633
A stereochemical inversion that occurs at a chiral center during a chemical reaction, resulting in a change in the configuration of the molecule. This phenomenon is characteristic of SN2 reactions, where the nucleophile attacks from the side opposite to the leaving group. It leads to a product with the opposite stereochemistry.
| Identifier | MLC-T-CHM-012633 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| References | PAC, 1996, 68, 2193. 'Basic terminology of stereochemistry (IUPAC Recommendations 1996)' on page 2221 (https://doi.org/10.1351/pac199668122193) |
| See also | Chiral; Identity reaction; Inversion; Relative configuration; Transformation |
Record as JSON
{
"id": "MLC-T-CHM-012633",
"term": "Walden inversion",
"field": "Chemistry",
"definition": "A stereochemical inversion that occurs at a chiral center during a chemical reaction, resulting in a change in the configuration of the molecule. This phenomenon is characteristic of SN2 reactions, where the nucleophile attacks from the side opposite to the leaving group. It leads to a product with the opposite stereochemistry.",
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"chiral",
"identity reaction",
"inversion",
"relative configuration",
"transformation"
],
"references": [
"PAC, 1996, 68, 2193. 'Basic terminology of stereochemistry (IUPAC Recommendations 1996)' on page 2221 (https://doi.org/10.1351/pac199668122193)"
],
"url": "https://mlchart.com/terminology/chemistry/walden-inversion/"
}
Record 13,476 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.