Asymmetric transformation
Term · Chemistry · MLC-T-CHM-000865
A process in which a racemic mixture is converted into a single enantiomer or diastereomer, often through a dynamic equilibrium between the enantiomers or diastereomers under chiral conditions. This can involve crystallization, epimerization, or other reactions that favor the formation of one stereoisomer. The process can achieve a theoretical yield of 100% of a single stereoisomer.
| Identifier | MLC-T-CHM-000865 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| Synonyms | deracemization |
| References | PAC, 1996, 68, 2193. 'Basic terminology of stereochemistry (IUPAC Recommendations 1996)' on page 2200 (https://doi.org/10.1351/pac199668122193) |
| See also | Asymmetric; Chiral; Crystallization; Diastereoisomerism; Enantiomer; Equilibration; Racemate; Racemic; Solubility; Stereoconvergence; Transformation |
Record as JSON
{
"id": "MLC-T-CHM-000865",
"term": "Asymmetric transformation",
"field": "Chemistry",
"definition": "A process in which a racemic mixture is converted into a single enantiomer or diastereomer, often through a dynamic equilibrium between the enantiomers or diastereomers under chiral conditions. This can involve crystallization, epimerization, or other reactions that favor the formation of one stereoisomer. The process can achieve a theoretical yield of 100% of a single stereoisomer.",
"synonyms": [
"deracemization"
],
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"asymmetric",
"chiral",
"crystallization",
"diastereoisomerism",
"enantiomer",
"equilibration",
"racemate",
"racemic",
"solubility",
"stereoconvergence",
"transformation"
],
"references": [
"PAC, 1996, 68, 2193. 'Basic terminology of stereochemistry (IUPAC Recommendations 1996)' on page 2200 (https://doi.org/10.1351/pac199668122193)"
],
"url": "https://mlchart.com/terminology/chemistry/asymmetric-transformation/"
}
Record 931 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.