Asymmetric induction
Term · Chemistry · MLC-T-CHM-000859
The preferential formation of one enantiomer or diastereomer over another during a chemical reaction, influenced by a chiral center already present in the reactant or reagent. This phenomenon leads to the generation of new chiral centers with a specific stereochemical outcome. It is a key concept in asymmetric synthesis for controlling the stereochemistry of products.
| Identifier | MLC-T-CHM-000859 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| References | PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1086 (https://doi.org/10.1351/pac199466051077); PAC, 1996, 68, 2193. 'Basic terminology of stereochemistry (IUPAC Recommendations 1996)' on page 2200 (https://doi.org/10.1351/pac199668122193) |
| See also | Catalyst; Chiral; Diastereoisomerism; Enantiomer |
Record as JSON
{
"id": "MLC-T-CHM-000859",
"term": "Asymmetric induction",
"field": "Chemistry",
"definition": "The preferential formation of one enantiomer or diastereomer over another during a chemical reaction, influenced by a chiral center already present in the reactant or reagent. This phenomenon leads to the generation of new chiral centers with a specific stereochemical outcome. It is a key concept in asymmetric synthesis for controlling the stereochemistry of products.",
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"catalyst",
"chiral",
"diastereoisomerism",
"enantiomer"
],
"references": [
"PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1086 (https://doi.org/10.1351/pac199466051077)",
"PAC, 1996, 68, 2193. 'Basic terminology of stereochemistry (IUPAC Recommendations 1996)' on page 2200 (https://doi.org/10.1351/pac199668122193)"
],
"url": "https://mlchart.com/terminology/chemistry/asymmetric-induction/"
}
Record 925 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.