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Local fraction volatilized

Term · Chemistry · MLC-T-CHM-006738

A ratio of the amount of analyte in the gaseous state, as free atoms, molecules and radicals, to the amount of analyte already desolvated, evaluated at a defined point in a flame such as the observation zone. It decreases as the desolvated particles get larger, because large dry aerosol particles volatilize incompletely. It is one factor in the overall efficiency of atomization, alongside the local fractions desolvated and atomized.

Table 1. Record
IdentifierMLC-T-CHM-006738
FieldChemistry
SubjectAnalytical Chemistry
ReferencesOrange Book, 2nd ed., p. 168 (https://media.iupac.org/publications/analytical_compendium/); PAC, 1986, 58, 1737. 'Quantities and units in clinical chemistry: Nebulizer and flame properties in flame emission and absorption spectrometry (Recommendations 1986)' on page 1741 (https://doi.org/10.1351/pac198658121737)
See alsoSubstance fraction
Record as JSON
{
  "id": "MLC-T-CHM-006738",
  "term": "Local fraction volatilized",
  "field": "Chemistry",
  "definition": "A ratio of the amount of analyte in the gaseous state, as free atoms, molecules and radicals, to the amount of analyte already desolvated, evaluated at a defined point in a flame such as the observation zone. It decreases as the desolvated particles get larger, because large dry aerosol particles volatilize incompletely. It is one factor in the overall efficiency of atomization, alongside the local fractions desolvated and atomized.",
  "subject": "Analytical Chemistry",
  "see_also": [
    "substance fraction"
  ],
  "references": [
    "Orange Book, 2nd ed., p. 168 (https://media.iupac.org/publications/analytical_compendium/)",
    "PAC, 1986, 58, 1737. 'Quantities and units in clinical chemistry: Nebulizer and flame properties in flame emission and absorption spectrometry (Recommendations 1986)' on page 1741 (https://doi.org/10.1351/pac198658121737)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/local-fraction-volatilized/"
}

Record 7,137 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.