Local molar polarizability
Term · Chemistry · MLC-T-CHM-006740
The complex molar polarizability of a medium, calculated from its complex dielectric function or refractive index with the Lorentz-Lorenz relation, which assumes that each molecule feels the Lorentz local field. Its imaginary part gives an absorption band free of the long-range dielectric effects that distort the shapes of very strong bands. Its SI unit is J⁻¹ C² m² mol⁻¹.
| Identifier | MLC-T-CHM-006740 |
|---|---|
| Field | Chemistry |
| Subject | Analytical Chemistry |
| Synonyms | molar polarizability |
| References | PAC, 2021, 93, 647. 'Glossary of methods and terms used in analytical spectroscopy (IUPAC Recommendations 2019)' on page 753 (https://doi.org/10.1515/pac-2019-0203) |
| See also | Band shape |
Record as JSON
{
"id": "MLC-T-CHM-006740",
"term": "Local molar polarizability",
"field": "Chemistry",
"definition": "The complex molar polarizability of a medium, calculated from its complex dielectric function or refractive index with the Lorentz-Lorenz relation, which assumes that each molecule feels the Lorentz local field. Its imaginary part gives an absorption band free of the long-range dielectric effects that distort the shapes of very strong bands. Its SI unit is J⁻¹ C² m² mol⁻¹.",
"synonyms": [
"molar polarizability"
],
"subject": "Analytical Chemistry",
"see_also": [
"band shape"
],
"references": [
"PAC, 2021, 93, 647. 'Glossary of methods and terms used in analytical spectroscopy (IUPAC Recommendations 2019)' on page 753 (https://doi.org/10.1515/pac-2019-0203)"
],
"url": "https://mlchart.com/terminology/chemistry/local-molar-polarizability/"
}
Record 7,139 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.