Molar-mass dispersity
Term · Chemistry · MLC-T-CHM-007475
A measure of the breadth of the molar mass distribution in a polymer sample, indicating the heterogeneity of chain lengths. It is calculated as the ratio of the weight-average molar mass to the number-average molar mass. A value of 1.0 indicates a perfectly monodisperse sample, where all polymer chains have the same molar mass.
| Identifier | MLC-T-CHM-007475 |
|---|---|
| Field | Chemistry |
| Subject | Polymer |
| Synonyms | molecular-weight dispersity; relative-molar-mass dispersity; relative-molecular-mass dispersity |
| References | PAC, 2015, 87, 71. 'Definitions of terms relating to individual macromolecules, macromolecular assemblies, polymer solutions, and amorphous bulk polymers (IUPAC Recommendations 2014)' on page 88 (https://doi.org/10.1515/pac-2013-0201) |
| See also | Mass-average molar mass |
Record as JSON
{
"id": "MLC-T-CHM-007475",
"term": "Molar-mass dispersity",
"field": "Chemistry",
"definition": "A measure of the breadth of the molar mass distribution in a polymer sample, indicating the heterogeneity of chain lengths. It is calculated as the ratio of the weight-average molar mass to the number-average molar mass. A value of 1.0 indicates a perfectly monodisperse sample, where all polymer chains have the same molar mass.",
"synonyms": [
"molecular-weight dispersity",
"relative-molar-mass dispersity",
"relative-molecular-mass dispersity"
],
"subject": "Polymer",
"see_also": [
"mass-average molar mass"
],
"references": [
"PAC, 2015, 87, 71. 'Definitions of terms relating to individual macromolecules, macromolecular assemblies, polymer solutions, and amorphous bulk polymers (IUPAC Recommendations 2014)' on page 88 (https://doi.org/10.1515/pac-2013-0201)"
],
"url": "https://mlchart.com/terminology/chemistry/molar-mass-dispersity/"
}
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