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Odd-electron ion

Term · Chemistry · MLC-T-CHM-008193

An ion containing an unpaired electron in its ground electronic state or in one of its excited states. This results in the ion having a net electronic spin and being paramagnetic. An odd-electron ion is also known as a radical ion, and its formation is a common outcome of electron ionization in mass spectrometry, where a neutral molecule loses a single electron.

Table 1. Record
IdentifierMLC-T-CHM-008193
FieldChemistry
SubjectPhysical and Biophysical Chemistry
ReferencesPAC, 1991, 63, 1541. 'Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)' on page 1549 (https://doi.org/10.1351/pac199163101541)
See alsoRadical ion
Record as JSON
{
  "id": "MLC-T-CHM-008193",
  "term": "Odd-electron ion",
  "field": "Chemistry",
  "definition": "An ion containing an unpaired electron in its ground electronic state or in one of its excited states. This results in the ion having a net electronic spin and being paramagnetic. An odd-electron ion is also known as a radical ion, and its formation is a common outcome of electron ionization in mass spectrometry, where a neutral molecule loses a single electron.",
  "subject": "Physical and Biophysical Chemistry",
  "see_also": [
    "radical ion"
  ],
  "references": [
    "PAC, 1991, 63, 1541. 'Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)' on page 1549 (https://doi.org/10.1351/pac199163101541)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/odd-electron-ion/"
}

Record 8,709 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.