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Product development control

Term · Chemistry · MLC-T-CHM-009504

A type of reaction control where the structure of the transition state resembles the product more than the starting material. This implies that factors stabilizing the product will also stabilize the transition state, thus influencing the reaction rate and selectivity. It is often contrasted with reactant control, where the transition state resembles the reactants.

Table 1. Record
IdentifierMLC-T-CHM-009504
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1153 (https://doi.org/10.1351/pac199466051077)
See alsoKinetic control; Reaction coordinate; Steric-approach control; Thermodynamic control; Transition state
Record as JSON
{
  "id": "MLC-T-CHM-009504",
  "term": "Product development control",
  "field": "Chemistry",
  "definition": "A type of reaction control where the structure of the transition state resembles the product more than the starting material. This implies that factors stabilizing the product will also stabilize the transition state, thus influencing the reaction rate and selectivity. It is often contrasted with reactant control, where the transition state resembles the reactants.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "kinetic control",
    "reaction coordinate",
    "steric-approach control",
    "thermodynamic control",
    "transition state"
  ],
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1153 (https://doi.org/10.1351/pac199466051077)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/product-development-control/"
}

Record 10,090 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.