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Reacting bond rules

Term · Chemistry · MLC-T-CHM-009962

A set of qualitative principles used to predict the structure of transition states in organic reactions. These rules consider the changes in bond orders and charges as reactants transform into products. They provide a framework for understanding reaction mechanisms and predicting the effects of structural modifications on reaction rates.

Table 1. Record
IdentifierMLC-T-CHM-009962
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1158 (https://doi.org/10.1351/pac199466051077)
See alsoHammond principle; More O'Ferrall-Jencks diagram; Molecular entity; Transition state
Record as JSON
{
  "id": "MLC-T-CHM-009962",
  "term": "Reacting bond rules",
  "field": "Chemistry",
  "definition": "A set of qualitative principles used to predict the structure of transition states in organic reactions. These rules consider the changes in bond orders and charges as reactants transform into products. They provide a framework for understanding reaction mechanisms and predicting the effects of structural modifications on reaction rates.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "Hammond principle",
    "More O'Ferrall-Jencks diagram",
    "molecular entity",
    "transition state"
  ],
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1158 (https://doi.org/10.1351/pac199466051077)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/reacting-bond-rules/"
}

Record 10,592 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.