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Retention index

Term · Chemistry · MLC-T-CHM-010290

An index that places the retention of a sample component between those of two standard compounds that elute just before and just after it, calculated by interpolation. In the Kováts index for isothermal gas chromatography the standards are n-alkanes, the interpolation is logarithmic, and the index equals 100 times the carbon number of a hypothetical n-alkane with the same retention. Unlike raw retention times it does not depend on flow rate or column length, but it still depends on the stationary phase and the temperature.

Table 1. Record
IdentifierMLC-T-CHM-010290
FieldChemistry
SubjectAnalytical Chemistry
ReferencesOrange Book, 2nd ed., p. 108 (https://media.iupac.org/publications/analytical_compendium/); PAC, 1993, 65, 819. 'Nomenclature for chromatography (IUPAC Recommendations 1993)' on page 844 (https://doi.org/10.1351/pac199365040819)
See alsoRetention volumes; Alkanes; Chromatography
Record as JSON
{
  "id": "MLC-T-CHM-010290",
  "term": "Retention index",
  "field": "Chemistry",
  "definition": "An index that places the retention of a sample component between those of two standard compounds that elute just before and just after it, calculated by interpolation. In the Kováts index for isothermal gas chromatography the standards are n-alkanes, the interpolation is logarithmic, and the index equals 100 times the carbon number of a hypothetical n-alkane with the same retention. Unlike raw retention times it does not depend on flow rate or column length, but it still depends on the stationary phase and the temperature.",
  "subject": "Analytical Chemistry",
  "see_also": [
    "retention volumes",
    "alkanes",
    "chromatography"
  ],
  "references": [
    "Orange Book, 2nd ed., p. 108 (https://media.iupac.org/publications/analytical_compendium/)",
    "PAC, 1993, 65, 819. 'Nomenclature for chromatography (IUPAC Recommendations 1993)' on page 844 (https://doi.org/10.1351/pac199365040819)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/retention-index/"
}

Record 10,937 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.