Rotational diffusion coefficient
Term · Chemistry · MLC-T-CHM-010424
A measure of the rate at which a molecule reorients itself due to random thermal motions in a fluid. This coefficient quantifies the average angular displacement per unit time for a rotating particle. It is inversely proportional to the rotational friction coefficient and is often determined through techniques like dynamic light scattering or nuclear magnetic resonance spectroscopy.
| Identifier | MLC-T-CHM-010424 |
|---|---|
| Field | Chemistry |
| Subject | Physical and Biophysical Chemistry |
| References | PAC, 1972, 31, 577. 'Manual of Symbols and Terminology for Physicochemical Quantities and Units, Appendix II: Definitions, Terminology and Symbols in Colloid and Surface Chemistry' on page 617 (https://doi.org/10.1351/pac197231040577) |
| See also | Angle; Rotational diffusion |
Record as JSON
{
"id": "MLC-T-CHM-010424",
"term": "Rotational diffusion coefficient",
"field": "Chemistry",
"definition": "A measure of the rate at which a molecule reorients itself due to random thermal motions in a fluid. This coefficient quantifies the average angular displacement per unit time for a rotating particle. It is inversely proportional to the rotational friction coefficient and is often determined through techniques like dynamic light scattering or nuclear magnetic resonance spectroscopy.",
"subject": "Physical and Biophysical Chemistry",
"see_also": [
"angle",
"rotational diffusion"
],
"references": [
"PAC, 1972, 31, 577. 'Manual of Symbols and Terminology for Physicochemical Quantities and Units, Appendix II: Definitions, Terminology and Symbols in Colloid and Surface Chemistry' on page 617 (https://doi.org/10.1351/pac197231040577)"
],
"url": "https://mlchart.com/terminology/chemistry/rotational-diffusion-coefficient/"
}
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