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Thermoreversible junction point

Term · Chemistry · MLC-T-CHM-011987

A region within a polymer network where chains are interconnected through non-covalent bonds that form or break in response to temperature changes. These points are responsible for the physical cross-linking that creates a gel structure from a polymer solution upon cooling. Unlike permanent covalent cross-links, these junctions arise from weaker physical interactions, such as hydrogen bonding, ionic aggregation, or the formation of microcrystalline domains.

Table 1. Record
IdentifierMLC-T-CHM-011987
FieldChemistry
SubjectPolymer
ReferencesPAC, 2007, 79, 1801. 'Definitions of terms relating to the structure and processing of sols, gels, networks, and inorganic-organic hybrid materials (IUPAC Recommendations 2007)' on page 1820 (https://doi.org/10.1351/pac200779101801)
See alsoJunction point
Record as JSON
{
  "id": "MLC-T-CHM-011987",
  "term": "Thermoreversible junction point",
  "field": "Chemistry",
  "definition": "A region within a polymer network where chains are interconnected through non-covalent bonds that form or break in response to temperature changes. These points are responsible for the physical cross-linking that creates a gel structure from a polymer solution upon cooling. Unlike permanent covalent cross-links, these junctions arise from weaker physical interactions, such as hydrogen bonding, ionic aggregation, or the formation of microcrystalline domains.",
  "subject": "Polymer",
  "see_also": [
    "junction point"
  ],
  "references": [
    "PAC, 2007, 79, 1801. 'Definitions of terms relating to the structure and processing of sols, gels, networks, and inorganic-organic hybrid materials (IUPAC Recommendations 2007)' on page 1820 (https://doi.org/10.1351/pac200779101801)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/thermoreversible-junction-point/"
}

Record 12,786 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.