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Transient crosslink

Term · Chemistry · MLC-T-CHM-012222

A non-covalent bond or physical association between polymer chains that forms and breaks reversibly under specific conditions. These temporary links arise from interactions such as hydrogen bonding, ionic aggregation, or metal-ligand coordination, in contrast to permanent covalent crosslinks. The characteristic lifetime of these reversible junctions is temperature-dependent and determines the material's viscoelastic response, including its flow and relaxation behavior.

Table 1. Record
IdentifierMLC-T-CHM-012222
FieldChemistry
SubjectPolymer
ReferencesPAC, 2007, 79, 1801. 'Definitions of terms relating to the structure and processing of sols, gels, networks, and inorganic-organic hybrid materials (IUPAC Recommendations 2007)' on page 1819 (https://doi.org/10.1351/pac200779101801)
See alsoCrosslink; Intermolecular; Intramolecular; Unstable
Record as JSON
{
  "id": "MLC-T-CHM-012222",
  "term": "Transient crosslink",
  "field": "Chemistry",
  "definition": "A non-covalent bond or physical association between polymer chains that forms and breaks reversibly under specific conditions. These temporary links arise from interactions such as hydrogen bonding, ionic aggregation, or metal-ligand coordination, in contrast to permanent covalent crosslinks. The characteristic lifetime of these reversible junctions is temperature-dependent and determines the material's viscoelastic response, including its flow and relaxation behavior.",
  "subject": "Polymer",
  "see_also": [
    "crosslink",
    "intermolecular",
    "intramolecular",
    "unstable"
  ],
  "references": [
    "PAC, 2007, 79, 1801. 'Definitions of terms relating to the structure and processing of sols, gels, networks, and inorganic-organic hybrid materials (IUPAC Recommendations 2007)' on page 1819 (https://doi.org/10.1351/pac200779101801)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/transient-crosslink/"
}

Record 13,031 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.