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Adiabatic electron transfer

Term · Chemistry · MLC-T-CHM-000250

An electron transfer process where the electronic state of the system changes smoothly and continuously along the reaction coordinate, without any electronic transitions to other states. This implies that the electronic coupling between the donor and acceptor is strong. The probability of electron transfer is high in such a process.

Table 1. Record
IdentifierMLC-T-CHM-000250
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2227 (https://doi.org/10.1351/pac199668122223)
See alsoElectron transfer; Marcus equation; Adiabatic; Diabatic electron transfer
Record as JSON
{
  "id": "MLC-T-CHM-000250",
  "term": "Adiabatic electron transfer",
  "field": "Chemistry",
  "definition": "An electron transfer process where the electronic state of the system changes smoothly and continuously along the reaction coordinate, without any electronic transitions to other states. This implies that the electronic coupling between the donor and acceptor is strong. The probability of electron transfer is high in such a process.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "electron transfer",
    "Marcus equation",
    "adiabatic",
    "diabatic electron transfer"
  ],
  "references": [
    "PAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2227 (https://doi.org/10.1351/pac199668122223)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/adiabatic-electron-transfer/"
}

Record 265 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.