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Adiabatic photoreaction

Term · Chemistry · MLC-T-CHM-000253

A photochemical reaction that occurs entirely on a single potential energy surface, meaning the electronic state of the molecule does not change during the course of the reaction. The excited state formed upon light absorption directly transforms into a product without undergoing intersystem crossing or internal conversion. This type of reaction is relatively rare.

Table 1. Record
IdentifierMLC-T-CHM-000253
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2227 (https://doi.org/10.1351/pac199668122223)
See alsoDiabatic photoreaction; Excited state
Record as JSON
{
  "id": "MLC-T-CHM-000253",
  "term": "Adiabatic photoreaction",
  "field": "Chemistry",
  "definition": "A photochemical reaction that occurs entirely on a single potential energy surface, meaning the electronic state of the molecule does not change during the course of the reaction. The excited state formed upon light absorption directly transforms into a product without undergoing intersystem crossing or internal conversion. This type of reaction is relatively rare.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "diabatic photoreaction",
    "excited state"
  ],
  "references": [
    "PAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2227 (https://doi.org/10.1351/pac199668122223)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/adiabatic-photoreaction/"
}

Record 268 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.