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Alkene photodimerization

Term · Chemistry · MLC-T-CHM-012853

A photochemical reaction where two alkene molecules combine to form a cyclobutane dimer upon absorption of light. This process involves the excitation of one or both alkene molecules to an electronically excited state, followed by bond formation. The reaction can proceed through concerted or stepwise mechanisms, yielding different stereoisomers.

Table 1. Record
IdentifierMLC-T-CHM-012853
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 2007, 79, 293. 'Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)' on page 301 (https://doi.org/10.1351/pac200779030293)
See alsoAlkenes; Electronically excited state; Alkene photocycloaddition
Record as JSON
{
  "id": "MLC-T-CHM-012853",
  "term": "Alkene photodimerization",
  "field": "Chemistry",
  "definition": "A photochemical reaction where two alkene molecules combine to form a cyclobutane dimer upon absorption of light. This process involves the excitation of one or both alkene molecules to an electronically excited state, followed by bond formation. The reaction can proceed through concerted or stepwise mechanisms, yielding different stereoisomers.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "alkenes",
    "electronically excited state",
    "alkene photocycloaddition"
  ],
  "references": [
    "PAC, 2007, 79, 293. 'Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)' on page 301 (https://doi.org/10.1351/pac200779030293)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/alkene-photodimerization/"
}

Record 418 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.