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Ene reaction

Term · Chemistry · MLC-T-CHM-003914

A pericyclic reaction involving an alkene with an allylic hydrogen (the 'ene') and a compound containing a multiple bond (the 'enophile'). The reaction results in the formation of a new sigma bond, migration of the ene's double bond, and transfer of the allylic hydrogen to the enophile. This is a concerted reaction, often proceeding through a six-membered transition state.

Table 1. Record
IdentifierMLC-T-CHM-003914
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1112 (https://doi.org/10.1351/pac199466051077)
See alsoRetro
Record as JSON
{
  "id": "MLC-T-CHM-003914",
  "term": "Ene reaction",
  "field": "Chemistry",
  "definition": "A pericyclic reaction involving an alkene with an allylic hydrogen (the 'ene') and a compound containing a multiple bond (the 'enophile'). The reaction results in the formation of a new sigma bond, migration of the ene's double bond, and transfer of the allylic hydrogen to the enophile. This is a concerted reaction, often proceeding through a six-membered transition state.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "retro"
  ],
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1112 (https://doi.org/10.1351/pac199466051077)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/ene-reaction/"
}

Record 4,146 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.