MLchartDataset catalogue

Retro

Term · Chemistry · MLC-T-CHM-010300

A prefix with several established meanings. In carotenoid and retinoid names it shows that every single and double bond of the conjugated polyene chain has shifted by one position, as in retro-retinoids; in peptide names it marks the reversed amino acid sequence; and in reaction names it marks the reverse of a known reaction, as in the retro-Diels-Alder cleavage of a cyclohexene into a diene and a dienophile. A retro-inverso peptide combines the reversed sequence with inverted chirality at each residue.

Table 1. Record
IdentifierMLC-T-CHM-010300
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesBlue Book Guide, p. 32 (https://doi.org/10.1351/pac199971071327); PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1363 (https://doi.org/10.1351/pac199567081307)
See alsoCarotenoids; Peptides; Retinoids; Sequence
Record as JSON
{
  "id": "MLC-T-CHM-010300",
  "term": "Retro",
  "field": "Chemistry",
  "definition": "A prefix with several established meanings. In carotenoid and retinoid names it shows that every single and double bond of the conjugated polyene chain has shifted by one position, as in retro-retinoids; in peptide names it marks the reversed amino acid sequence; and in reaction names it marks the reverse of a known reaction, as in the retro-Diels-Alder cleavage of a cyclohexene into a diene and a dienophile. A retro-inverso peptide combines the reversed sequence with inverted chirality at each residue.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "carotenoids",
    "peptides",
    "retinoids",
    "sequence"
  ],
  "references": [
    "Blue Book Guide, p. 32 (https://doi.org/10.1351/pac199971071327)",
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1363 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/retro/"
}

Record 10,948 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.