MLchartDataset catalogue

Apical

Term · Chemistry · MLC-T-CHM-000731

Describing a position in a trigonal bipyramidal molecular geometry that lies along the axis perpendicular to the equatorial plane. Substituents in these positions are typically 180 degrees apart from each other and 90 degrees from the equatorial substituents. In phosphorus pentachloride (PCl5), the two chlorine atoms along the main axis are apical.

Table 1. Record
IdentifierMLC-T-CHM-000731
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1996, 68, 2193. 'Basic terminology of stereochemistry (IUPAC Recommendations 1996)' on page 2199 (https://doi.org/10.1351/pac199668122193)
See alsoAxial; Central atom; Equatorial
Record as JSON
{
  "id": "MLC-T-CHM-000731",
  "term": "Apical",
  "field": "Chemistry",
  "definition": "Describing a position in a trigonal bipyramidal molecular geometry that lies along the axis perpendicular to the equatorial plane. Substituents in these positions are typically 180 degrees apart from each other and 90 degrees from the equatorial substituents. In phosphorus pentachloride (PCl5), the two chlorine atoms along the main axis are apical.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "axial",
    "central atom",
    "equatorial"
  ],
  "references": [
    "PAC, 1996, 68, 2193. 'Basic terminology of stereochemistry (IUPAC Recommendations 1996)' on page 2199 (https://doi.org/10.1351/pac199668122193)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/apical/"
}

Record 782 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.