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Catalytic chain termination

Term · Chemistry · MLC-T-CHM-001717

A process in polymerization where a catalyst facilitates the cessation of chain growth, often by transferring a hydrogen atom or other group to the propagating species. This leads to the formation of a dead polymer chain and regenerates the catalyst. It is a termination pathway distinct from bimolecular termination in radical polymerization.

Table 1. Record
IdentifierMLC-T-CHM-001717
FieldChemistry
SubjectPolymer
ReferencesPAC, 2022, 94, 1093. 'Terminology for chain polymerization (IUPAC Recommendations 2021)' on page 1116 (https://doi.org/10.1515/pac-2020-1211)
See alsoPropagating species; Reversible-deactivation radical polymerization
Record as JSON
{
  "id": "MLC-T-CHM-001717",
  "term": "Catalytic chain termination",
  "field": "Chemistry",
  "definition": "A process in polymerization where a catalyst facilitates the cessation of chain growth, often by transferring a hydrogen atom or other group to the propagating species. This leads to the formation of a dead polymer chain and regenerates the catalyst. It is a termination pathway distinct from bimolecular termination in radical polymerization.",
  "subject": "Polymer",
  "see_also": [
    "propagating species",
    "reversible-deactivation radical polymerization"
  ],
  "references": [
    "PAC, 2022, 94, 1093. 'Terminology for chain polymerization (IUPAC Recommendations 2021)' on page 1116 (https://doi.org/10.1515/pac-2020-1211)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/catalytic-chain-termination/"
}

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