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Chiral mobile phase

Term · Chemistry · MLC-T-CHM-002002

A liquid or supercritical fluid used in chromatography that contains a chiral selector, enabling the separation of enantiomers. The chiral selector in the mobile phase interacts selectively with the enantiomers of the analyte, forming transient diastereomeric complexes. These complexes then exhibit different affinities for the stationary phase, leading to their separation.

Table 1. Record
IdentifierMLC-T-CHM-002002
FieldChemistry
SubjectAnalytical Chemistry
ReferencesPAC, 1997, 69, 1469. 'Analytical chiral separation methods (IUPAC Recommendations 1997)' on page 1472 (https://doi.org/10.1351/pac199769071469)
See alsoChiral selector
Record as JSON
{
  "id": "MLC-T-CHM-002002",
  "term": "Chiral mobile phase",
  "field": "Chemistry",
  "definition": "A liquid or supercritical fluid used in chromatography that contains a chiral selector, enabling the separation of enantiomers. The chiral selector in the mobile phase interacts selectively with the enantiomers of the analyte, forming transient diastereomeric complexes. These complexes then exhibit different affinities for the stationary phase, leading to their separation.",
  "subject": "Analytical Chemistry",
  "see_also": [
    "chiral selector"
  ],
  "references": [
    "PAC, 1997, 69, 1469. 'Analytical chiral separation methods (IUPAC Recommendations 1997)' on page 1472 (https://doi.org/10.1351/pac199769071469)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/chiral-mobile-phase/"
}

Record 2,147 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.