MLchartDataset catalogue

Chiral recognition

Term · Chemistry · MLC-T-CHM-002003

The process by which a chiral molecule or agent selectively interacts with one enantiomer of a chiral substrate over the other. This discrimination is based on the formation of transient diastereomeric complexes that have different energies and stabilities. Chiral recognition is the fundamental principle behind enantioselective synthesis, the chromatographic separation of enantiomers, and the specific action of many enzymes and drug receptors.

Table 1. Record
IdentifierMLC-T-CHM-002003
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 2022, 94, 353. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 2021)' on page 386 (https://doi.org/10.1515/pac-2018-1010)
See alsoMolecular recognition
Record as JSON
{
  "id": "MLC-T-CHM-002003",
  "term": "Chiral recognition",
  "field": "Chemistry",
  "definition": "The process by which a chiral molecule or agent selectively interacts with one enantiomer of a chiral substrate over the other. This discrimination is based on the formation of transient diastereomeric complexes that have different energies and stabilities. Chiral recognition is the fundamental principle behind enantioselective synthesis, the chromatographic separation of enantiomers, and the specific action of many enzymes and drug receptors.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "molecular recognition"
  ],
  "references": [
    "PAC, 2022, 94, 353. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 2021)' on page 386 (https://doi.org/10.1515/pac-2018-1010)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/chiral-recognition/"
}

Record 2,148 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.