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Distortionless enhancement by polarization transfer

Term · Chemistry · MLC-T-CHM-003338

A nuclear magnetic resonance (NMR) spectroscopy pulse sequence designed to enhance the signals of carbon-13 nuclei and differentiate between CH, CH2, and CH3 groups. It achieves this by transferring polarization from protons to carbons, leading to increased sensitivity. The technique provides information on the number of attached protons for each carbon.

Table 1. Record
IdentifierMLC-T-CHM-003338
FieldChemistry
SubjectAnalytical Chemistry
ReferencesPAC, 2021, 93, 647. 'Glossary of methods and terms used in analytical spectroscopy (IUPAC Recommendations 2019)' on page 686 (https://doi.org/10.1515/pac-2019-0203)
See alsoFlip angle; Nuclear magnetic resonance spectroscopy
Record as JSON
{
  "id": "MLC-T-CHM-003338",
  "term": "Distortionless enhancement by polarization transfer",
  "field": "Chemistry",
  "definition": "A nuclear magnetic resonance (NMR) spectroscopy pulse sequence designed to enhance the signals of carbon-13 nuclei and differentiate between CH, CH2, and CH3 groups. It achieves this by transferring polarization from protons to carbons, leading to increased sensitivity. The technique provides information on the number of attached protons for each carbon.",
  "subject": "Analytical Chemistry",
  "see_also": [
    "flip angle",
    "nuclear magnetic resonance spectroscopy"
  ],
  "references": [
    "PAC, 2021, 93, 647. 'Glossary of methods and terms used in analytical spectroscopy (IUPAC Recommendations 2019)' on page 686 (https://doi.org/10.1515/pac-2019-0203)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/distortionless-enhancement-by-polarization-transfer/"
}

Record 3,549 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.