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Electrocapillarity

Term · Chemistry · MLC-T-CHM-003650

The study of the relationship between the interfacial tension at a metal-electrolyte boundary and the electric potential difference across that interface. The interfacial tension of a liquid metal electrode, such as mercury, changes as the applied potential is varied. This phenomenon is described by the Lippmann equation, which relates the change in surface tension to the surface charge density and the potential.

Table 1. Record
IdentifierMLC-T-CHM-003650
FieldChemistry
SubjectPhysical and Biophysical Chemistry
ReferencesPAC, 1986, 58, 437. 'Interphases in systems of conducting phases (Recommendations 1985)' on page 446 (https://doi.org/10.1351/pac198658030437)
Record as JSON
{
  "id": "MLC-T-CHM-003650",
  "term": "Electrocapillarity",
  "field": "Chemistry",
  "definition": "The study of the relationship between the interfacial tension at a metal-electrolyte boundary and the electric potential difference across that interface. The interfacial tension of a liquid metal electrode, such as mercury, changes as the applied potential is varied. This phenomenon is described by the Lippmann equation, which relates the change in surface tension to the surface charge density and the potential.",
  "subject": "Physical and Biophysical Chemistry",
  "references": [
    "PAC, 1986, 58, 437. 'Interphases in systems of conducting phases (Recommendations 1985)' on page 446 (https://doi.org/10.1351/pac198658030437)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/electrocapillarity/"
}

Record 3,874 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.