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Equivalent hydrodynamic volume

Term · Chemistry · MLC-T-CHM-004080

The volume occupied by a hypothetical hard sphere that possesses the same hydrodynamic properties as a macromolecule in solution. This value is often determined from chromatographic measurements, such as size-exclusion chromatography. It reflects the effective size of a polymer chain, including any associated solvent molecules, as it moves through a fluid.

Table 1. Record
IdentifierMLC-T-CHM-004080
FieldChemistry
SubjectPolymer
ReferencesPAC, 2015, 87, 71. 'Definitions of terms relating to individual macromolecules, macromolecular assemblies, polymer solutions, and amorphous bulk polymers (IUPAC Recommendations 2014)' on page 103 (https://doi.org/10.1515/pac-2013-0201)
Record as JSON
{
  "id": "MLC-T-CHM-004080",
  "term": "Equivalent hydrodynamic volume",
  "field": "Chemistry",
  "definition": "The volume occupied by a hypothetical hard sphere that possesses the same hydrodynamic properties as a macromolecule in solution. This value is often determined from chromatographic measurements, such as size-exclusion chromatography. It reflects the effective size of a polymer chain, including any associated solvent molecules, as it moves through a fluid.",
  "subject": "Polymer",
  "references": [
    "PAC, 2015, 87, 71. 'Definitions of terms relating to individual macromolecules, macromolecular assemblies, polymer solutions, and amorphous bulk polymers (IUPAC Recommendations 2014)' on page 103 (https://doi.org/10.1515/pac-2013-0201)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/equivalent-hydrodynamic-volume/"
}

Record 4,319 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.