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Hydrodynamically equivalent sphere

Term · Chemistry · MLC-T-CHM-005467

A hypothetical sphere that exhibits the same hydrodynamic properties, such as sedimentation coefficient or diffusion coefficient, as a real, irregularly shaped macromolecule in a given solvent. This concept simplifies the analysis of complex polymer shapes by allowing their behavior to be modeled as an equivalent spherical particle. Its radius is known as the hydrodynamic radius.

Table 1. Record
IdentifierMLC-T-CHM-005467
FieldChemistry
SubjectPolymer
ReferencesPurple Book, 1st ed., p. 60 (http://old.iupac.org/publications/books/author/metanomski.html)
See alsoDiffusion; Macromolecule
Record as JSON
{
  "id": "MLC-T-CHM-005467",
  "term": "Hydrodynamically equivalent sphere",
  "field": "Chemistry",
  "definition": "A hypothetical sphere that exhibits the same hydrodynamic properties, such as sedimentation coefficient or diffusion coefficient, as a real, irregularly shaped macromolecule in a given solvent. This concept simplifies the analysis of complex polymer shapes by allowing their behavior to be modeled as an equivalent spherical particle. Its radius is known as the hydrodynamic radius.",
  "subject": "Polymer",
  "see_also": [
    "diffusion",
    "macromolecule"
  ],
  "references": [
    "Purple Book, 1st ed., p. 60 (http://old.iupac.org/publications/books/author/metanomski.html)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/hydrodynamically-equivalent-sphere/"
}

Record 5,790 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.