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Herz compounds

Term · Chemistry · MLC-T-CHM-005224

A class of cationic heterocyclic compounds, specifically 1,2,3-dithiazolylium salts, which contain a five-membered ring composed of two sulfur atoms, one nitrogen atom, and two carbon atoms. These compounds are typically synthesized via the Herz reaction, where an aniline derivative or a related aromatic amine reacts with sulfur monochloride. The reaction was first described by the chemist Richard Herz in 1922 and provides a route to sulfur-nitrogen heterocycles used as precursors for dyes and other functional materials.

Table 1. Record
IdentifierMLC-T-CHM-005224
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1339 (https://doi.org/10.1351/pac199567081307)
Record as JSON
{
  "id": "MLC-T-CHM-005224",
  "term": "Herz compounds",
  "field": "Chemistry",
  "definition": "A class of cationic heterocyclic compounds, specifically 1,2,3-dithiazolylium salts, which contain a five-membered ring composed of two sulfur atoms, one nitrogen atom, and two carbon atoms. These compounds are typically synthesized via the Herz reaction, where an aniline derivative or a related aromatic amine reacts with sulfur monochloride. The reaction was first described by the chemist Richard Herz in 1922 and provides a route to sulfur-nitrogen heterocycles used as precursors for dyes and other functional materials.",
  "subject": "Organic and Biomolecular Chemistry",
  "references": [
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1339 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/herz-compounds/"
}

Record 5,536 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.