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Heteronuclear multiple-quantum correlation with additional TOCSY transfer

Term · Chemistry · MLC-T-CHM-005261

A two-dimensional nuclear magnetic resonance (NMR) experiment that combines heteronuclear multiple-quantum correlation (HMQC) with total correlation spectroscopy (TOCSY) transfer. This technique correlates the chemical shifts of a heteronucleus (e.g., ¹³C or ¹⁵N) with protons that are coupled to it, and also with other protons within the same spin system. It provides information about both direct heteronuclear couplings and extended proton spin networks, often displayed as a 2D spectrum.

Table 1. Record
IdentifierMLC-T-CHM-005261
FieldChemistry
SubjectAnalytical Chemistry
ReferencesPAC, 2021, 93, 647. 'Glossary of methods and terms used in analytical spectroscopy (IUPAC Recommendations 2019)' on page 691 (https://doi.org/10.1515/pac-2019-0203)
See alsoHeteronuclear multiple bond correlation NMR; Spin system; Total correlation spectroscopy
Record as JSON
{
  "id": "MLC-T-CHM-005261",
  "term": "Heteronuclear multiple-quantum correlation with additional TOCSY transfer",
  "field": "Chemistry",
  "definition": "A two-dimensional nuclear magnetic resonance (NMR) experiment that combines heteronuclear multiple-quantum correlation (HMQC) with total correlation spectroscopy (TOCSY) transfer. This technique correlates the chemical shifts of a heteronucleus (e.g., ¹³C or ¹⁵N) with protons that are coupled to it, and also with other protons within the same spin system. It provides information about both direct heteronuclear couplings and extended proton spin networks, often displayed as a 2D spectrum.",
  "subject": "Analytical Chemistry",
  "see_also": [
    "heteronuclear multiple bond correlation NMR",
    "spin system",
    "total correlation spectroscopy"
  ],
  "references": [
    "PAC, 2021, 93, 647. 'Glossary of methods and terms used in analytical spectroscopy (IUPAC Recommendations 2019)' on page 691 (https://doi.org/10.1515/pac-2019-0203)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/heteronuclear-multiple-quantum-correlation-with-additional-tocsy-transfer/"
}

Record 5,574 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.