Heteronuclear single quantum multiple-bond correlation
Term · Chemistry · MLC-T-CHM-005266
A two-dimensional nuclear magnetic resonance (NMR) experiment that correlates the chemical shift of a proton with the chemical shift of a heteronucleus, such as carbon-13, to which it is coupled over two or more bonds. This technique is used to establish long-range connectivity within a molecule, providing structural information beyond direct attachments. The experiment relies on scalar coupling constants, which are typically smaller for longer-range interactions.
| Identifier | MLC-T-CHM-005266 |
|---|---|
| Field | Chemistry |
| Subject | Analytical Chemistry |
| References | PAC, 2021, 93, 647. 'Glossary of methods and terms used in analytical spectroscopy (IUPAC Recommendations 2019)' on page 692 (https://doi.org/10.1515/pac-2019-0203) |
| See also | Heteronuclear single quantum correlation |
Record as JSON
{
"id": "MLC-T-CHM-005266",
"term": "Heteronuclear single quantum multiple-bond correlation",
"field": "Chemistry",
"definition": "A two-dimensional nuclear magnetic resonance (NMR) experiment that correlates the chemical shift of a proton with the chemical shift of a heteronucleus, such as carbon-13, to which it is coupled over two or more bonds. This technique is used to establish long-range connectivity within a molecule, providing structural information beyond direct attachments. The experiment relies on scalar coupling constants, which are typically smaller for longer-range interactions.",
"subject": "Analytical Chemistry",
"see_also": [
"heteronuclear single quantum correlation"
],
"references": [
"PAC, 2021, 93, 647. 'Glossary of methods and terms used in analytical spectroscopy (IUPAC Recommendations 2019)' on page 692 (https://doi.org/10.1515/pac-2019-0203)"
],
"url": "https://mlchart.com/terminology/chemistry/heteronuclear-single-quantum-multiple-bond-correlation/"
}
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