Homotopic
Term · Chemistry · MLC-T-CHM-005387
Describing atoms or groups of a molecule that are interchanged by a proper rotation axis, C2, C3 or higher, so that replacing either one gives identical compounds. Homotopic groups are equivalent under all conditions, including in a chiral environment. The three chlorines of chloroform, interchanged by a C3 axis, are homotopic, whereas the two methylene hydrogens of ethanol are enantiotopic.
| Identifier | MLC-T-CHM-005387 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| References | PAC, 1996, 68, 2193. 'Basic terminology of stereochemistry (IUPAC Recommendations 1996)' on page 2210 (https://doi.org/10.1351/pac199668122193) |
| See also | Chiral; Prochirality |
Record as JSON
{
"id": "MLC-T-CHM-005387",
"term": "Homotopic",
"field": "Chemistry",
"definition": "Describing atoms or groups of a molecule that are interchanged by a proper rotation axis, C2, C3 or higher, so that replacing either one gives identical compounds. Homotopic groups are equivalent under all conditions, including in a chiral environment. The three chlorines of chloroform, interchanged by a C3 axis, are homotopic, whereas the two methylene hydrogens of ethanol are enantiotopic.",
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"chiral",
"prochirality"
],
"references": [
"PAC, 1996, 68, 2193. 'Basic terminology of stereochemistry (IUPAC Recommendations 1996)' on page 2210 (https://doi.org/10.1351/pac199668122193)"
],
"url": "https://mlchart.com/terminology/chemistry/homotopic/"
}
Record 5,708 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.