Isokinetic relationship

{
  "id": "MLC-T-CHM-006193",
  "term": "Isokinetic relationship",
  "field": "Chemistry",
  "definition": "A linear relationship observed between the activation enthalpy and activation entropy for a series of related chemical reactions. This relationship implies that the activation free energy is constant at a specific temperature, known as the isokinetic temperature. It is a manifestation of the compensation effect in reaction kinetics.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "compensation effect",
    "enthalpy of activation",
    "entropy of activation",
    "isoequilibrium relationship",
    "isoselective relationship"
  ],
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1129 (https://doi.org/10.1351/pac199466051077)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/isokinetic-relationship/"
}