MLchartDataset catalogue

Isoselective relationship

Term · Chemistry · MLC-T-CHM-006215

A linear relationship observed when the selectivity of a reaction or process is plotted against a varying parameter, such as temperature, for a series of related systems. This implies that the mechanism governing selectivity remains consistent across the series. Such relationships are often used in physical organic chemistry to analyze reaction pathways.

Table 1. Record
IdentifierMLC-T-CHM-006215
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1130 (https://doi.org/10.1351/pac199466051077)
See alsoIsoequilibrium relationship; Isokinetic relationship
Record as JSON
{
  "id": "MLC-T-CHM-006215",
  "term": "Isoselective relationship",
  "field": "Chemistry",
  "definition": "A linear relationship observed when the selectivity of a reaction or process is plotted against a varying parameter, such as temperature, for a series of related systems. This implies that the mechanism governing selectivity remains consistent across the series. Such relationships are often used in physical organic chemistry to analyze reaction pathways.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "isoequilibrium relationship",
    "isokinetic relationship"
  ],
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1130 (https://doi.org/10.1351/pac199466051077)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/isoselective-relationship/"
}

Record 6,598 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.