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Isoequilibrium relationship

Term · Chemistry · MLC-T-CHM-006185

A linear relationship observed between the enthalpy and entropy changes for a series of related equilibrium processes. This relationship implies that the free energy change for these processes is constant at a specific temperature, known as the isoequilibrium temperature. It is a manifestation of the compensation effect in chemical equilibria.

Table 1. Record
IdentifierMLC-T-CHM-006185
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1128 (https://doi.org/10.1351/pac199466051077)
See alsoEnthalpy; Entropy; Isokinetic relationship
Record as JSON
{
  "id": "MLC-T-CHM-006185",
  "term": "Isoequilibrium relationship",
  "field": "Chemistry",
  "definition": "A linear relationship observed between the enthalpy and entropy changes for a series of related equilibrium processes. This relationship implies that the free energy change for these processes is constant at a specific temperature, known as the isoequilibrium temperature. It is a manifestation of the compensation effect in chemical equilibria.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "enthalpy",
    "entropy",
    "isokinetic relationship"
  ],
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1128 (https://doi.org/10.1351/pac199466051077)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/isoequilibrium-relationship/"
}

Record 6,566 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.