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Isotopic molecular ion

Term · Chemistry · MLC-T-CHM-006248

A molecular ion that contains one or more atoms of a less abundant naturally occurring isotope, such as carbon-13, deuterium, or bromine-81, in place of the most abundant one. Its peaks sit beside the monoisotopic molecular ion peak, usually at higher m/z, although a lighter minor isotope such as boron-10 puts a peak at lower m/z. Their relative intensities follow natural isotope abundances, as in the roughly 1:1 pair of peaks produced by a bromine atom.

Table 1. Record
IdentifierMLC-T-CHM-006248
FieldChemistry
SubjectPhysical and Biophysical Chemistry
ReferencesPAC, 1991, 63, 1541. 'Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)' on page 1549 (https://doi.org/10.1351/pac199163101541)
See alsoIsotopes
Record as JSON
{
  "id": "MLC-T-CHM-006248",
  "term": "Isotopic molecular ion",
  "field": "Chemistry",
  "definition": "A molecular ion that contains one or more atoms of a less abundant naturally occurring isotope, such as carbon-13, deuterium, or bromine-81, in place of the most abundant one. Its peaks sit beside the monoisotopic molecular ion peak, usually at higher m/z, although a lighter minor isotope such as boron-10 puts a peak at lower m/z. Their relative intensities follow natural isotope abundances, as in the roughly 1:1 pair of peaks produced by a bromine atom.",
  "subject": "Physical and Biophysical Chemistry",
  "see_also": [
    "isotopes"
  ],
  "references": [
    "PAC, 1991, 63, 1541. 'Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)' on page 1549 (https://doi.org/10.1351/pac199163101541)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/isotopic-molecular-ion/"
}

Record 6,634 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.