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Magic angle spinning

Term · Chemistry · MLC-T-CHM-006898

A technique used in solid-state nuclear magnetic resonance (NMR) spectroscopy to average out anisotropic interactions, such as chemical shift anisotropy and dipolar coupling, which broaden spectral lines. The sample is rapidly rotated at a specific angle (54.74 degrees) relative to the static magnetic field. This rotation effectively averages these orientation-dependent interactions to zero, resulting in sharper, more resolved spectral peaks.

Table 1. Record
IdentifierMLC-T-CHM-006898
FieldChemistry
SubjectAnalytical Chemistry
ReferencesPAC, 2021, 93, 647. 'Glossary of methods and terms used in analytical spectroscopy (IUPAC Recommendations 2019)' on page 695 (https://doi.org/10.1515/pac-2019-0203)
See alsoAnisotropic; Solid-state nuclear magnetic resonance spectroscopy
Record as JSON
{
  "id": "MLC-T-CHM-006898",
  "term": "Magic angle spinning",
  "field": "Chemistry",
  "definition": "A technique used in solid-state nuclear magnetic resonance (NMR) spectroscopy to average out anisotropic interactions, such as chemical shift anisotropy and dipolar coupling, which broaden spectral lines. The sample is rapidly rotated at a specific angle (54.74 degrees) relative to the static magnetic field. This rotation effectively averages these orientation-dependent interactions to zero, resulting in sharper, more resolved spectral peaks.",
  "subject": "Analytical Chemistry",
  "see_also": [
    "anisotropic",
    "solid-state nuclear magnetic resonance spectroscopy"
  ],
  "references": [
    "PAC, 2021, 93, 647. 'Glossary of methods and terms used in analytical spectroscopy (IUPAC Recommendations 2019)' on page 695 (https://doi.org/10.1515/pac-2019-0203)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/magic-angle-spinning/"
}

Record 7,305 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.