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Magnetic circular dichroism

Term · Chemistry · MLC-T-CHM-006899

A spectroscopic effect where a substance placed in a strong magnetic field parallel to a light beam absorbs left and right circularly polarized light to different extents. This difference in absorption is plotted as a function of wavelength to produce an MCD spectrum, which provides information about the electronic states of a molecule. The technique is particularly sensitive to paramagnetic species and transitions involving degenerate electronic states, which are split by the magnetic field via the Zeeman effect.

Table 1. Record
IdentifierMLC-T-CHM-006899
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 2007, 79, 293. 'Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)' on page 368 (https://doi.org/10.1351/pac200779030293)
See alsoZeeman effect; Anti; Diamagnetic; Dichroism; Infrared; Optical activity; Paramagnetic; Wavelength
Record as JSON
{
  "id": "MLC-T-CHM-006899",
  "term": "Magnetic circular dichroism",
  "field": "Chemistry",
  "definition": "A spectroscopic effect where a substance placed in a strong magnetic field parallel to a light beam absorbs left and right circularly polarized light to different extents. This difference in absorption is plotted as a function of wavelength to produce an MCD spectrum, which provides information about the electronic states of a molecule. The technique is particularly sensitive to paramagnetic species and transitions involving degenerate electronic states, which are split by the magnetic field via the Zeeman effect.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "Zeeman effect",
    "anti",
    "diamagnetic",
    "dichroism",
    "infrared",
    "optical activity",
    "paramagnetic",
    "wavelength"
  ],
  "references": [
    "PAC, 2007, 79, 293. 'Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)' on page 368 (https://doi.org/10.1351/pac200779030293)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/magnetic-circular-dichroism/"
}

Record 7,306 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.