Magnetic circular dichroism
Term · Chemistry · MLC-T-CHM-006899
A spectroscopic effect where a substance placed in a strong magnetic field parallel to a light beam absorbs left and right circularly polarized light to different extents. This difference in absorption is plotted as a function of wavelength to produce an MCD spectrum, which provides information about the electronic states of a molecule. The technique is particularly sensitive to paramagnetic species and transitions involving degenerate electronic states, which are split by the magnetic field via the Zeeman effect.
| Identifier | MLC-T-CHM-006899 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| References | PAC, 2007, 79, 293. 'Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)' on page 368 (https://doi.org/10.1351/pac200779030293) |
| See also | Zeeman effect; Anti; Diamagnetic; Dichroism; Infrared; Optical activity; Paramagnetic; Wavelength |
Record as JSON
{
"id": "MLC-T-CHM-006899",
"term": "Magnetic circular dichroism",
"field": "Chemistry",
"definition": "A spectroscopic effect where a substance placed in a strong magnetic field parallel to a light beam absorbs left and right circularly polarized light to different extents. This difference in absorption is plotted as a function of wavelength to produce an MCD spectrum, which provides information about the electronic states of a molecule. The technique is particularly sensitive to paramagnetic species and transitions involving degenerate electronic states, which are split by the magnetic field via the Zeeman effect.",
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"Zeeman effect",
"anti",
"diamagnetic",
"dichroism",
"infrared",
"optical activity",
"paramagnetic",
"wavelength"
],
"references": [
"PAC, 2007, 79, 293. 'Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)' on page 368 (https://doi.org/10.1351/pac200779030293)"
],
"url": "https://mlchart.com/terminology/chemistry/magnetic-circular-dichroism/"
}
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