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Micellar electrokinetic chromatography

Term · Chemistry · MLC-T-CHM-007288

A mode of electrokinetic chromatography in which separation is based on the differential partitioning of analytes between a background electrolyte and micelles. The micelles, formed by adding a surfactant above its critical micelle concentration, act as a pseudostationary phase that moves at a different velocity from the bulk electroosmotic flow. This technique is particularly suited for the separation of neutral molecules, which do not migrate in a conventional capillary electrophoresis system.

Table 1. Record
IdentifierMLC-T-CHM-007288
FieldChemistry
SubjectAnalytical Chemistry
Synonymsmicellar electrokinetic capillary chromatography
ReferencesPAC, 2017, 90, 181. 'Terminology of separation methods (IUPAC Recommendations 2017)' on page 218 (https://doi.org/10.1515/pac-2017-0111)
See alsoElectrokinetic chromatography
Record as JSON
{
  "id": "MLC-T-CHM-007288",
  "term": "Micellar electrokinetic chromatography",
  "field": "Chemistry",
  "definition": "A mode of electrokinetic chromatography in which separation is based on the differential partitioning of analytes between a background electrolyte and micelles. The micelles, formed by adding a surfactant above its critical micelle concentration, act as a pseudostationary phase that moves at a different velocity from the bulk electroosmotic flow. This technique is particularly suited for the separation of neutral molecules, which do not migrate in a conventional capillary electrophoresis system.",
  "synonyms": [
    "micellar electrokinetic capillary chromatography"
  ],
  "subject": "Analytical Chemistry",
  "see_also": [
    "electrokinetic chromatography"
  ],
  "references": [
    "PAC, 2017, 90, 181. 'Terminology of separation methods (IUPAC Recommendations 2017)' on page 218 (https://doi.org/10.1515/pac-2017-0111)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/micellar-electrokinetic-chromatography/"
}

Record 7,724 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.